师资队伍

李翔

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李翔

海河学者特聘教授,博士生导师

所属系部:化工系

办公电话:+86-22-60601864

办公地点:泰达中校区8号楼A-413

Emaillixiang@tust.edu.cn

个人简介

李翔,博士,“海河学者特聘教授,博士生导师。2004年博士毕业于大连理工大学后留校工作,2011年被聘为博士生导师。其间,于2005-2006年在瑞士联邦工学院(ETH, Zurich)做博士后研究,师从国际知名催化专家、Journal of Catalysis前主编Roel Prins教授。20188月被天津科技大学聘为海河学者特聘教授。长期从事馏分油加氢精制(加氢脱硫和加氢脱氮)、生物燃料加氢脱氧、不饱和烃选择加氢以及介孔和介微孔复合分子筛的合成及其催化应用等方面的研究工作,擅长X射线吸收能谱表征。2008年被国际催化理事会授予青年科学家奖”(Young Scientist Award)2009年获辽宁省自然科学三等奖(第二完成人)。到目前为止作为负责人承担国家自然科学基金青年基金1项,国家自然科学基金面上项目2项,还承担了辽宁省自然科学基金以及中石油科技创新基金等项目。作为骨干参加了国家自然科学基金青年基金、国家自然科学基金重点项目、国家自然科学基金联合基金重点项目及 “863”子课题等项目。在Angew. Chem.J. Catal.等国内外知名期刊和重要会议上发表论文上百篇。参与编写英文国际教材一部,中文教材两部和著作一部。是《催化学报》(影响因子2.813)青年编委、国家自然科学基金通讯评审专家。

研究方向

1. 加氢精制

2. 选择加氢

3. 加氢脱氧

4. 介孔及介微孔分子筛合成及催化应用

学术成果

代表性论著:

1. Qiang Sheng, Xiang Li*, Roel Prins, Chunjing Liu, Qinglan Hao, Shaozhang Chen. Understanding the Reduction of Transition‐metal Phosphates to Transition‐metal Phosphides by Combining Temperature‐programmed Reduction and Infrared Spectroscopy. Angewandte Chemie-International Edition, 2021, in press, doi: 10.1002/anie.202100767.

2. Xiang Li*, XuerongZhou, Lin Wang, Jinyin Lv, Shengnan Liu, Roel Prins, Anjie Wang, Qiang Sheng. Mechanistic studies and kinetics of the desulfurization of 2-phenylcyclohexanethiol over sulfided Mo, Ni-Mo, and Co-Mo on γ-Al2O3. Journal of Catalysis, 2021, in press, doi: 10.1016/j.jcat.2021.01.017.

3. Xuerong, Zhou, Xiang Li*, Roel Prins, Jinyin Lv, Anjie Wang. Qiang Sheng. Hydrodesulfurization of dibenzothiophene and its hydrogenated intermediates over bulk CoP and Co2P catalysts with stoichiometric P/Co ratios, Journal of Catalysis, 2021, 394, 167-180.

4. Xuerong Zhou, Xiang Li*; Roel Prins, Anjie Wang, Lin Wang, Shengnan Liu, Qiang Sheng. Desulfurization of 2-phenylcyclohexanethiol over transition-metal phosphides, Journal of Catalysis, 2020, 383: 331-342.

5. Shuang Chu, Xiang Li*, Xuerong Zhou, Roel Prins, Qureshi Waqas, Anjie Wang, Qiang Sheng, Qinglan Hao, Preparation of Ni2P Supported on Al2O3 and B2O Mixed Oxides by Temperature-Programmed Reduction of Phosphate Precursors with Low P/Ni Ratios, Topics in Catalysis, 2020, 63, 1379-1387.

6. Xiang Li, Song Tian, Anjie Wang, Roel Prins, Congcong Li, Yongying Chen. XPS study of a bulk WP hydrodesulfurization catalyst. Journal of Catalysis, 2017, 352, 557-561 (Priority Communication and Featured Article).

7. Chao Dong, Xiang Li*, Anjie Wang, Yongying Chen, Influences of sodium and potassium cations on the hydrodesulfurization performances of Pd and Pt catalysts supported on siliceous MCM-41. Catalysis Today, 2017, 297, 124-130.

8. Chao Dong, Xiang Li*, Anjie Wang, Yongying Chen, Influence of nanoscale distribution of Pd particles in the mesopores of MCM-41 on the catalytic performance of Pd/MCM-41. Catalysis Communications, 2017, 100, 219-222.

9. Wei Wang, Xiang Li*, Anjie Wang, Zhichao Sun, Yongying Chen, Plasma synthesis of Ni2P from mixtures of NiCl2 and hypophosphites. Topics in Catalysis, 2017, 60(12-14), 987-996.

10. 李翔,王安杰,柳广厦,李聪聪,陈永英. 芳香杂环含硫化合物C–S键断裂方式. 石油学报(石油加工),2017336),1039-1052.(特约综述).

11. Xiang Li, Jianpeng Feng, Jingyu Guo, Anjie Wang, Roel Prins, Xinping Duan, Yongying Chen. Preparation of Ni2P/Al2O3 by temperature-programmed reduction of a phosphate precursor with a low P/Ni ratio. Journal of Catalysis, 2016, 334, 116-119.

12. Song Tian, Xiang Li*, Anjie Wang, Roel Prins, Yongying Chen, Yongkang Hu. Facile preparation of Ni2P with a sulfur-containing surface layer by low-temperature reduction of Ni2P2S6. Angewandte Chemie-International Edition, 2016, 12, 4030-4034.

13. Wei Wang, Xiang Li*, Zhichao Sun, Anjie Wang, Yingya Liu, Yongying Chen, XinPing Duan. Influences of calcination and reduction methods on the preparation of Ni2P/SiO2 and its hydrodenitrogenation performance. Applied Catalysis A: General, 2016, 509, 45-51.

14. Lei Yang, Xiang Li*, Anjie Wang, Roel Prins, Yongying Chen, Xinping Duan. Hydrodesulfurization of dibenzothiophene, 4,6-dimethyldibenzothiophene, and their hydrogenated intermediates over bulk tungsten phosphide. Journal of Catalysis, 2015, 330, 330-343.

15. Xiang Li, Luda Liu, Anjie Wang, Mengyan Wang, Yao Wang, Yongying Chen. Creation of oxygen vacancies in MoO3/SiO2 by thermal decomposition of pre-impregnated citric acid under N2 and their positive role in oxidative desulfurization of dibenzothiophene. Catalysis Letters, 2014, 144(3), 531-537.

16. Xiang Li, Zhichao Sun, Anjie Wang, Yao Wang, Xinping Duan, Yongying Chen. XAS study of Ni2P/MCM-41 passivated by O2/He and H2S/H. Catalysis Communications, 2014, 43, 21-24.

17. Lei Yang, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang, Yongying Chen, Xinping Duan. Hydrodesulfurization of 4,6-dimethyldibenzothiophene and its hydrogenated intermediates over bulk Ni2P. Journal of Catalysis, 2014, 317, 144-152.

18. Jin Bai, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang. Different role of H2S and dibenzothiophene in the incorporation of sulfur in the surface of bulk MoP during hydrodesulfurization. Journal of Catalysis, 2013, 300, 197-200.

19. Jin Bai, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang. Hydrodesulfurization of dibenzothiophene and its hydrogenated intermediates over bulk MoP. Journal of Catalysis, 2012, 287, 161-169.

20. Xiang Li, Anjie Wang, Marina Egorova, Roel Prins. Kinetics of the HDS of 4,6-dimethyldibenzothiophene and its hydrogenated intermediates over sulfided Mo and NiMo on γ -Al2O3, Journal of Catalysis, 2007, 250, 283-293.

专著或教材:

1. Roel Prins, Anjie Wang, Xiang Li. Introduction to Heterogeneous Catalysis. World Scientific Publishing (UK) Ltd., 2016

2. 王桂茹,王安杰,刘靖,郭新闻,郭洪臣,李翔,催化剂与催化作用(第4版),大连理工大学出版社,2015

3. 王安杰(主编),张守臣(副主编),李翔(副主编),化学反应工程学(第二版),化学工业出版社,2018

4. 王桂茹,王安杰,刘靖,郭新闻,郭洪臣,李翔,催化剂与催化作用:石油、非石油资源催化转化制取能源及化学品,大连理工大学出版社,2015

荣誉奖励

1. 青年科学家奖(Young Scientist Award),国际催化理事会,2008

2. 辽宁省自然科学三等奖(第二完成人),2009