正高级(教授、研究员、正高级实验师)

李翔

海河学者特聘教授,博士生导师

所属系别:化工系

办公电话:+86-22-60601864

办公地点:泰达中校区8号楼A-413

电子邮箱:lixiang@tust.edu.cn

个人简介

李翔,博士,教授,博士生导师。2004年博士毕业于大连理工大学后留校工作,2011年被聘为博士生导师。间,于2005-2006年在瑞士联邦工学院(ETH, Zurich)做博士后研究,合作导师为Roel Prins教授。20188月被天津科技大学聘为海河学者特聘教授。长期从事馏分油加氢精制(加氢脱硫和加氢脱氮)、生物燃料加氢脱氧、不饱和烃选择加氢、介孔和介微孔复合分子筛催化材料、酸碱催化和微通道连续流反应过程强化等方面的研究工作。2008年被国际催化理事会授予青年科学家奖(Young Scientist Award)2009年获辽宁省自然科学三等奖(第二完成人)。到目前为止作为负责人承担国家自然科学基金青年基金1项,国家自然科学基金面上项目2项,还承担了辽宁省自然科学基金、天津市自然科学基金重点项目以及中石油科技创新基金等项目。作为骨干参加了国家自然科学基金重点项目、国家自然科学基金联合基金重点项目及863子课题等项目。在Angew. Chem.ACS Catal.J. Catal.等国内外知名期刊和重要会议上发表论文上百篇。参与编写英文国际教材一部,中文教材两部和著作一部。是《催化学报》青年编委、国家自然科学基金通讯评审专家。

研究方向

1. 加氢精制

2. 选择加氢

3. 加氢脱氧

4. 酸碱催化

5. 微通道连续流反应过程强化

学术成果

代表性论著及专利:

1. Yang Hu, Siyu Kuang, Xuerong Zhou, Xiang Li,* Sheng Zhang,* Roel Prins, Chenxi Zhang, Sensen Shang, and Qiang Sheng. Insights into correlations among the hydrodesulfurization, hydrodenitrogenation, and hydrogen evolution reactions over molybdenum phosphide catalysts modified by cerium oxide. ACS Catalysis, 2023, 13, 13786-13803.

2. Pengfei Shi, Xiang Li*, Xuerong Zhou, Roel Prins, Qiang Sheng, Sensen Shang. Chunjing Liu. Desulfurization of 2-phenylcyclohexanethiol over Pd and Pt catalysts on γ-Al2O3. Journal of Catalysis, 2023, 428, 115198.

3. Ming He, Xiang Li*, Anjie Wang, Yang Hu, Qiang Sheng, Sensen Shang. Controllable synthesis of nanostructured nickel phosphosulfide by reduction of mixtures of Na4P2S6 and NiCl2 with low P/Ni ratios in hydrogen plasma. Catalysis Today, 2023, 423, 113999.

4. Shuang Chu, Xiang Li*, Roel Prins, Chunhua Wang, Yingya Liu, Anjie Wang, Qiang Sheng. Preparation of ultrasmall Ni2P nanoparticles with low P/Ni ratios supported on SiO2 and an Al2O3-B2O3 mixed oxide for dibenzothiophene hydrodesulfurization. Journal of Catalysis, 2023, 420, 110-122.

5. Chunhua Wang, Xiang Li*, Ying-Ya Liu, Anjie Wang, Qiang Sheng, Chen-Xi Zhang. Insight into metal-support interactions from the hydrodesulfurization of dibenzothiophene over Pd catalysts supported on UiO-66 and its aminofunctionalized analogues. Journal of Catalysis, 2022, 407, 333-341.

6. Ben Chen, Bowen Hui, Yuting Dong, Qiang Sheng, Xiang Li, Qinglan Hao, Chunjing Liu. Distributions of Ni in MCM-41 for the hydrogenation of N-ethylcarbazole. Fuel, 2022, 324, 124405- 124405.

7. Qiang Sheng, Xiang Li*, Roel Prins, Chunjing Liu, Qinglan Hao, Shaozhang Chen. Understanding the reduction of transitionmetal phosphates to transitionmetal phosphides by combining temperatureprogrammed reduction and infrared spectroscopy. Angewandte Chemie-International Edition, 2021, 60, 11180-11183.

8. Xiang Li*, XuerongZhou, Lin Wang, Jinyin Lv, Shengnan Liu, Roel Prins, Anjie Wang, Qiang Sheng. Mechanistic studies and kinetics of the desulfurization of 2-phenylcyclohexanethiol over sulfided Mo, Ni-Mo, and Co-Mo on γ-Al2O3. Journal of Catalysis, 2021, 403, 43-55.

9. Xuerong, Zhou, Xiang Li*, Roel Prins, Jinyin Lv, Anjie Wang. Qiang Sheng. Hydrodesulfurization of dibenzothiophene and its hydrogenated intermediates over bulk CoP and Co2P catalysts with stoichiometric P/Co ratios, Journal of Catalysis, 2021, 394, 167-180.

10. Xuerong Zhou, Xiang Li*; Roel Prins, Anjie Wang, Lin Wang, Shengnan Liu, Qiang Sheng. Desulfurization of 2-phenylcyclohexanethiol over transition-metal phosphides, Journal of Catalysis, 2020, 383: 331-342.

11. Shuang Chu, Xiang Li*, Xuerong Zhou, Roel Prins, Qureshi Waqas, Anjie Wang, Qiang Sheng, Qinglan Hao, Preparation of Ni2P supported on Al2O3 and B2O3 mixed oxides by temperature-programmed reduction of phosphate precursors with low P/Ni ratios, Topics in Catalysis, 2020, 63, 1379-1387.

12. Xiang Li, Song Tian, Anjie Wang, Roel Prins, Congcong Li, Yongying Chen. XPS study of a bulk WP hydrodesulfurization catalyst. Journal of Catalysis, 2017, 352, 557-561 (Priority Communication and Featured Article).

13. Chao Dong, Xiang Li*, Anjie Wang, Yongying Chen, Influences of sodium and potassium cations on the hydrodesulfurization performances of Pd and Pt catalysts supported on siliceous MCM-41. Catalysis Today, 2017, 297, 124-130.

14. Chao Dong, Xiang Li*, Anjie Wang, Yongying Chen, Influence of nanoscale distribution of Pd particles in the mesopores of MCM-41 on the catalytic performance of Pd/MCM-41. Catalysis Communications, 2017, 100, 219-222.

15. Wei Wang, Xiang Li*, Anjie Wang, Zhichao Sun, Yongying Chen, Plasma synthesis of Ni2P from mixtures of NiCl2 and hypophosphites. Topics in Catalysis, 2017, 60(12-14), 987-996.

16. 李翔,王安杰,柳广厦,李聪聪,陈永英. 芳香杂环含硫化合物CS键断裂方式. 石油学报(石油加工),2017336),1039-1052.(特约综述).

17. Xiang Li, Jianpeng Feng, Jingyu Guo, Anjie Wang, Roel Prins, Xinping Duan, Yongying Chen. Preparation of Ni2P/Al2O3 by temperature-programmed reduction of a phosphate precursor with a low P/Ni ratio. Journal of Catalysis, 2016, 334, 116-119.

18. Song Tian, Xiang Li*, Anjie Wang, Roel Prins, Yongying Chen, Yongkang Hu. Facile preparation of Ni2P with a sulfur-containing surface layer by low-temperature reduction of Ni2P2S6. Angewandte Chemie-International Edition, 2016, 12, 4030-4034.

19. Wei Wang, Xiang Li*, Zhichao Sun, Anjie Wang, Yingya Liu, Yongying Chen, XinPing Duan. Influences of calcination and reduction methods on the preparation of Ni2P/SiO2 and its hydrodenitrogenation performance. Applied Catalysis A: General, 2016, 509, 45-51.

20. Lei Yang, Xiang Li*, Anjie Wang, Roel Prins, Yongying Chen, Xinping Duan. Hydrodesulfurization of dibenzothiophene, 4,6-dimethyldibenzothiophene, and their hydrogenated intermediates over bulk tungsten phosphide. Journal of Catalysis, 2015, 330, 330-343.

21. Xiang Li, Luda Liu, Anjie Wang, Mengyan Wang, Yao Wang, Yongying Chen. Creation of oxygen vacancies in MoO3/SiO2 by thermal decomposition of pre-impregnated citric acid under N2 and their positive role in oxidative desulfurization of dibenzothiophene. Catalysis Letters, 2014, 144(3), 531-537.

22. Xiang Li, Zhichao Sun, Anjie Wang, Yao Wang, Xinping Duan, Yongying Chen. XAS study of Ni2P/MCM-41 passivated by O2/He and H2S/H2. Catalysis Communications, 2014, 43, 21-24.

23. Lei Yang, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang, Yongying Chen, Xinping Duan. Hydrodesulfurization of 4,6-dimethyldibenzothiophene and its hydrogenated intermediates over bulk Ni2P. Journal of Catalysis, 2014, 317, 144-152.

24. Jin Bai, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang. Different role of H2S and dibenzothiophene in the incorporation of sulfur in the surface of bulk MoP during hydrodesulfurization. Journal of Catalysis, 2013, 300, 197-200.

25. Jin Bai, Xiang Li*, Anjie Wang, Roel Prins, Yao Wang. Hydrodesulfurization of dibenzothiophene and its hydrogenated intermediates over bulk MoP. Journal of Catalysis, 2012, 287, 161-169.

26. Xiang Li, Anjie Wang, Marina Egorova, Roel Prins. Kinetics of the HDS of 4,6-dimethyldibenzothiophene and its hydrogenated intermediates over sulfided Mo and NiMo on γ -Al2O3, Journal of Catalysis, 2007, 250, 283-293.

专著或教材:

1. Roel Prins, Anjie Wang, Xiang Li, Foteini Sapountzi. Introduction to Heterogeneous Catalysis (Second Edition). World Scientific Publishing (UK) Ltd., 2022

2. Roel Prins, Anjie Wang, Xiang Li. Introduction to Heterogeneous Catalysis. World Scientific Publishing (UK) Ltd., 2016

3. 王桂茹,王安杰,刘靖,郭新闻,郭洪臣,李翔,催化剂与催化作用(第4版),大连理工大学出版社,2015

4. 王安杰(主编),张守臣(副主编),李翔(副主编),化学反应工程学(第二版),化学工业出版社,2018

5. 王桂茹,王安杰,刘靖,郭新闻,郭洪臣,李翔,催化剂与催化作用:石油、非石油资源催化转化制取能源及化学品,大连理工大学出版社,2015